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Title | Exciplexes of fullerene C60 with aromatic solvents |
Authors |
Ar'ev, I.A.
Lebovka, N.I. Ogenko, V.M. Tokmenko, I.I. |
ORCID | |
Keywords |
exciplexes with aromatics AN AMP ATP |
Type | Conference Papers |
Date of Issue | 2011 |
URI | http://essuir.sumdu.edu.ua/handle/123456789/20624 |
Publisher | Sumy State University |
License | |
Citation | Exciplexes of fullerene C60 with aromatic solvents [Текст] / I. A. Ar'ev, N. I. Lebovka, V. M. Ogenko, I. I. Tokmenko // Nanomaterials: applications & properties. Proceedings : 1-st International conference, Alushta, Crimea, 27-30 Semptember 2011 / Edited by: A. Pogrebnjak, T. Lyutyy, S. Protsenko. — Sumy : Sumy State University, 2011. — V.2, P.І. — C. 121-124. |
Abstract |
The solvent induced spectral shift method is applied to study stacking interactions between aromatic solvents molecules, such as benzene and toluene from one side, and solute fullerene C60. Ratios of high-energy transitions shifts to calculated shifts under dispersion interactions are considered. It is concluded that in contrast to aromatic molecules containing two or three rings which do not form complexes with aromatic solvents, fullerene forms exciplexes with high-energy excited states involved in more strong interactions rather than low-energy one. The higher is excited state, the stronger is interaction.
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