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Title | Block Copolymers Containing Poly(acrylic acid) for Stabilization of Vitamin E and Silver Nanoparticles in Aqueous Solutions |
Authors |
Permyakova, N.M.
Zheltonozhskaya, T.B. Maksin, V.I. Kaplunenko, V.G. Revko, O.V. |
ORCID | |
Keywords |
Block copolymer Intramolecular polycomplex Micellization Encapsulation Vitamin E Silver |
Type | Conference Papers |
Date of Issue | 2012 |
URI | http://essuir.sumdu.edu.ua/handle/123456789/34943 |
Publisher | Sumy State University |
License | Copyright not evaluated |
Citation | Block Copolymers Containing Poly(acrylic acid) for Stabilization of Vitamin E and Silver Nanoparticles in Aqueous Solutions [Текст] / N.M. Permyakova, T.B. Zheltonozhskaya, V.I. Maksin et al. // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V.1, No1. - 01PCN37 |
Abstract |
We have synthesized asymmetric di- and triblock copolymers containing chemically complementary
blocks of poly(acrylic acid) and methoxypoly(ethylene oxide) (PAAc-b-MOPEO) or poly(ethylene oxide)
(PAAc-b-PEO-b-PAAc) using a template radical block copolymerization process. At low pH, polyacid blocks
of these copolymers were protonated and formed the intramolecular polycomplexes (IntraPCs) with
MOPEO or PEO blocks. Due to both the intramolecular complex formation and hydrophobic interactions
between non-polar bound segments of the blocks, an intensive micellization in copolymer solutions at low
pH took place. Aqueous copolymer solutions were used as nanocontainers for encapsulation of poorly soluble vitamin E and as nanoreactors for the silver nanoclusters/nanoparticles formation.
When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/34943 |
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