Structure and Electrochemical Performance of Li[Li0.2Co0.4Mn0.4]O2 Cathode Material for Lithium Ion Battery by Co-precipitation Method

Abstract

The nano-structured Li[Li0.2Co0.4Mn0.4]O2 cathode material is synthesized by a co-precipitation method. X-ray diffraction shows that the synthesized material has a hexagonal α-NaFeO2 type structure with a space group R-3m. Scanning electron microscopy and transmission electron microscopy images show the homogeneous distribution with 100-200 nm. X-ray photoelectron spectroscopy results indicate that the oxi-dation states of Co and Mn in Li[Li0.2Co0.4Mn0.4]O2 are present in trivalence and tetravalence, respectively. The charge-discharge curves and cycling performance are analyzed in detail. The initial charge and dis-charge capacities are respectively 236.5 mAh g-1 and 140.3 mAh g-1 at the current density of 100 mA g-1 in the voltage range of 2.0-4.6 V. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35203