Harvesting and Electron-Exchange Energy Transfer by d0 Metallocene-based Organized Systems

Abstract

The present contribution will provide an up-to-date overview of novel experimental and theoretical (de-rived quantum-chemically) knowledge on photonics of group IV metallocene-based systems, also with re-spect to their prominent use in catalysis and photoluminescent sensor activity. We have developed photo-physical approach to study measurable properties of the frontier MOs of the complexes, estimate orbital nature of rare long-lived ligand-to-metal charge transfer (LMCT) excited states and also supramolecular interactions between basic components of catalytic systems for polymerization: d0-metal complexes and un-saturated hydrocarbon substrates in fluid systems. In the similar way, the photophysical approach is high-lighted to enable studying fine intermolecular interactions in homogeneous systems with low (catalytic) concentrations of metal complexes that cannot be achieved by other conventional methods. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35397