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Title | Conduction Mechanisms in Polypyrrole-Copper Nanocomposites |
Authors |
Praveenkumar, K.
Sankarappa, T. Ashwajeet, J.S. Ramanna, R. Sujatha, T. Kattimani, Jyoti Chandraprabha, G. |
ORCID | |
Keywords |
PPy-Cu nanocomposites Structure Polaron hopping Density of states |
Type | Article |
Date of Issue | 2015 |
URI | http://essuir.sumdu.edu.ua/handle/123456789/41514 |
Publisher | Sumy State University |
License | Copyright not evaluated |
Citation | K. Praveenkumar, T. Sankarappa, J.S. Ashwajeet, et al., J. Nano- Electron. Phys. 7 No 2, 02043 (2015) |
Abstract |
By mixing independently synthesized polypyrole and copper nanoparticles in different proportions,
nanocomposites were prepared. Bulk and surface structures were probed by X-ray diffraction and Scanning
electron microscopes. DC resistivity with temperature as a variable of all the composites has been investigated.
Conductivity has been calculated using resistivity and found it to be of the order 10 – 4 (Ω – 1m – 1),
which is greater by one order of magnitude than that reported for polypyrole nanoparticles. Temperature
behaviour of conductivity in all the samples revealed semiconducting nature. By applying Mott’s theory of
small polaron hopping, activation energy for conductivity at high temperature has been determined. Activation
energy is found to be increasing with increase in copper content in the composites. Using data deviated
from small polaron model, the density of states at Fermi level is calculated by employing the theory of
variable range hopping of polarons due to Mott. It is for the first time that PPy-Cu nanocomposites have
been probed for structural and temperature dependence of conductivity and conduction mechanisms operated
in these composites in different temperature regions have been understood. |
Appears in Collections: |
Журнал нано- та електронної фізики (Journal of nano- and electronic physics) |
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