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Title Water Splitting Photovoltaic-Photoelectrochemical GaAs/InGaAsP - WO3/BiVO4 Tandem Cell with Extremely Thin Absorber Photoanode Structure
Authors Kosar, S.
Pihosh, Y.
Turkevych, I.
Mawatari, K.
Uemura, J.
Kazoe, Y.
Makita, K.
Sugaya, T.
Matsui, T.
Fujita, D.
Tosa, M.
Struk, Y.M.
Kondo, M.
Kitamori, T.
ORCID
Keywords Photocatalysis
Photovoltaics
Renewable energy
Nanorods
Heterojunction
Type Conference Papers
Date of Issue 2015
URI http://essuir.sumdu.edu.ua/handle/123456789/42632
Publisher Sumy State University
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Citation Water Splitting Photovoltaic-Photoelectrochemical GaAs/InGaAsP - WO3/BiVO4 Tandem Cell with Extremely Thin Absorber Photoanode Structure [Текст] / S. Kosar, Yu. Pihosh, I. Turkevych et al. // Nanomaterials: Applications & Properties (NAP-2015) : Proceedings of the International Conference. — Sumy : Sumy State University, 2015. — V.4, No1. — 01NTF01.
Abstract We demonstrate highly efficient solar hydrogen generation via water splitting by photovoltaicphotoelectrochemical (PV-PEC) tandem device based on GaAs/InGaAsP (PV cell) and WO3/BiVO4 core/shell nanorods (PEC cell). We utilized extremely thin absorber (ETA) concept to design the WO3/BiVO4 core/shell heterojunction nanorods and obtained the highest efficiencies of photo-induced charge carriers generation, separation and transfer that are possible for the WO3/BiVO4 material combination. The PV-PEC tandem shows stable water splitting photocurrent of 6.56 mA cm-2 under standard AM1.5G solar light that corresponds to the record solar-to-hydrogen (STH) conversion efficiency of 8.1%.
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