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Title | Magnetic Properties and Local Parameters of Crystal Structure for BaFe[12]O[19] and SrFe[12]O[19] Hexagonal Ferrites |
Authors |
Shipko, M.N.
Kostishyn, V.G. Korovushkin, V.V. Isaev, I.M. Stepovich, M.A. Tikhonov, A.I. Savchenko, E.S. |
ORCID | |
Keywords |
hexagonal ferrites crystal structure mössbauer spectroscopy X-Ray diffraction solid phase reactions vacancies diffusion |
Type | Article |
Date of Issue | 2016 |
URI | http://essuir.sumdu.edu.ua/handle/123456789/47060 |
Publisher | Sumy State University |
License | |
Citation | Magnetic Properties and Local Parameters of Crystal Structure for BaFe[12]O[19] and SrFe[12]O[19] Hexagonal Ferrites [Текст] / M.N. Shipko, V.G. Kostishyn, V.V. Korovushkin [et al.] // Журнал нано- та електронної фізики. - 2016. - Т.8, №3. - 03004 |
Abstract |
It is shown that difference between magnetic properties of hexagonal ferrites BaFe[12]O[19] and SrFe[12]O[19] is connected with difference of electronic configurations of Ba2+ and Sr2+ ions, and their ionic radii. Replacement
of Ba2+ ions by Sr2+ ions that are smaller in size effects the degree of distortions of octahedrons located either in a hexagonal R-block or at its boundary with S-block. It contributes to a preferred localization of electrically active vacancies at the boundary of R- and S-blocks |
Appears in Collections: |
Журнал нано- та електронної фізики (Journal of nano- and electronic physics) |
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