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Title | Membrane Processes during the Regeneration of Galvanic Solution |
Other Titles |
Мембранні процеси при регенерації гальванічного розчину |
Authors |
Serdiuk, V.O.
Sklabinskyi, Vsevolod Ivanovych Bolshanina, Svitlana Borysivna Ivchenko, V.D. Qasim, M.N. Zaytseva, K.O. |
ORCID |
http://orcid.org/0000-0001-9388-5861 http://orcid.org/0000-0002-9482-8620 |
Keywords |
electrolysis galvanic solution ion-exchange membrane chromium-containing solution cadmium cations zinc cations електроліз гальванічний розчин іонообмінна мембрана хромовмісний розчин катіони кадмію катіони цинку |
Type | Article |
Date of Issue | 2018 |
URI | http://essuir.sumdu.edu.ua/handle/123456789/69187 |
Publisher | Sumy State University |
License | |
Citation | Membrane Processes during the Regeneration of Galvanic Solution [Текст] / V.O. Serdiuk, V.I. Sklavbinskyi, S.B. Bolshanina [et al.] // Журнал інженерних наук. - 2018. - Т. 5, № 2. - С. F1-F6. - DOI: 10.21272/jes.2018.5(2).f1. |
Abstract |
The process of Сd2+ and Zn2+ cations transfer through the cation exchange membrane
RALEX®CM-PES 11-66 in double-chamber electrolyzer was investigated. Anodic chamber electrolyte (analyte)
contained model solutions which imitates galvanic baths composition for passivation processes. The analyte contained
50 g/l sodium dichromate and 10 g/l sulfuric acid as main substances and impurities of Сd2+ and Zn2+ cations
in amount of 2.5 g/l of each. The electrolyte of cathode chamber is catholyte, contained 1 % solution of sulfuric acid.
The titanium grade BT-0 and lead grade C-0 were used as cathode and anode respectively. Cathode processes connected
with processes of ion migration through the membrane and metal release on cathode were studied. The creation
of volt-ampere curves in galvanodynamic mode was supplied by impulse potentiometer, tool for combined
measurements and silver chloride reference electrode. An increase of cathode overvoltage in the presence of cadmium
ions and decrease of cathode potential with the increase of temperature were proved. The pH range for intensive
reduction of metals was determined during investigations. Scanning electron microscopy with X-ray analysis was
used for estimation of cathode deposits elemental composition. It was established that metal atoms of cadmium and
zinc were presented in cathode deposits. Transference numbers of ions through cationic membrane were calculated
for cadmium and mixture of cations proved the effectiveness of chromium and zinc ions extraction from chromium
containing solutions. This process provides regeneration of galvanic solutions and maintains stable composition of
passivation bath. Використано метод побудови вольтамперних кривих у гальванодинамісному режимі за допомогою імпульсного потенціостату, приладів комбінованих вимірювань і хлор-срібного електроду порівняння. Доведено зростання перенапруги на катоді у присутності йонів кадмію та зниження потенціалу катода при підвищенні температури. |
Appears in Collections: |
Journal of Engineering Sciences / Журнал інженерних наук |
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JES_2018_02_F1-F6.pdf | 446.57 kB | Adobe PDF | 913197902 |
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