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Title Supported Gold Nanoparticles for the Oxidation of Benzyl Alcohol to Benzaldehyde
Authors Bagabas, A.
Alshammari, A.
Köckritz, A.
Kalevaru, V.N.
Martin, A.
ORCID
Keywords Gold nanoparticles
Gold catalyst
Oxidation of benzyl alcohol
Type Article
Date of Issue 2014
URI http://essuir.sumdu.edu.ua/handle/123456789/37122
Publisher Sumy State University
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Citation Supported Gold Nanoparticles for the Oxidation of Benzyl Alcohol to Benzaldehyde [Текст] / A. Bagabas, A. Alshammari, A. Ko"ckritz [et al.] // Nanomaterials: Applications & Properties (NAP-2014): Proceedings of the International Conference. – Sumy : Sumy State University, 2014. – V.3, No1. – 01PCSI12.
Abstract Nano-size Au particles deposited over different oxidic supports (MgO, CaO, ZrO2, TiO2, and Al2O3) by wet impregnation method was successfully prepared. Catalysts were characterized by TGA, ICP, BET surface area, XRD, and TEM, and then their catalytic activity were evaluated for the selective oxidation of benzyl alcohol to benzaldehyde. Among all tested catalysts, TiO2 supported Au nanoparticles exhibited the best catalytic activity with a benzyl alcohol conversion of 81% and benzaldehyde selectivity of 95% at 140 °C and 5 bar O2 in 4 h.
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