Synthesis and Structure of Intercalated Organo-inorganic Nanocomposites

Abstract

The synthesis and structure of organo–inorganic nanocomposites prepared by intercalation of monomers or polymers into the interlayer galleries of layered matrices are analyzed. General features and the mechanism of the intercalation process, as well as materials used for this purpose, mostly often naturally occurring materials (clays, silicates, layered phosphates, chalcogenides, and other moieties hosts), are discussed. Mechanisms governing the intercalation of monomers or polymer repeating units into the interlayer galleries as guests are compared. One of the most widespread and commercially important intracrystalline chemical reactions is the incorporation of monomer molecules into pores or layered lattices of the host substances with subsequent post-intercalation transformations into polymer, oligomer, or hybrid–sandwich products. Particular emphasis is placed on nanocomposites based on epoxy polymers and various mineral matrices. Basic application areas of hybrid nanomaterials are considered. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35070