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Item The potential of organic waste as a substrate for anaerobic digestion in Ukraine: trend definitions and environmental safety of the practices(Lviv Polytechnic National University, 2021) Черниш, Єлізавета Юріївна; Chernysh, Yelyzaveta Yuriivna; Shtepa, V.; Рой, Ігор Олександрович; Roi, Ihor Oleksandrovych; Чубур, Вікторія Сергіївна; Chubur, Viktoriia Serhiivna; Скворцова, Поліна Олексіївна; Skvortsova, Polina Oleksiivna; Ivlieva, A.; Danilov, D.This article is devoted to the analysis and prospects of using different types of organic waste to achieve environmental goals. Due to the unique climate and natural resources, Ukraine has significant potential for biomass, the processing of which should solve urgent problems with the disposal of waste, as well as the production of alternative energy sources and biofertilizers. The preferred substrates for anaerobic digestion in Ukraine, considering the technological feasibility, availability, and volume are animal manure (cattle, pigs), bird droppings, plant residues, industrial sludge, common sludges. After analyzing the statistics for 2015-2019, the groups of dominant wastes were identified, and with the help of the built-in function "TREND," the forecast of the waste potential with an organic component for 2021-2026 was constructed. Examining the obtained indicators for different types of waste, the reasons for the tendency of decrease or increase in their formation in the next five years were revealed. The direction of enhancing the sustainability of bioenergy, achieving environmental goals through the bioprocessing of organic waste associated with the ecological safety of production processes were discussed.Item Modeling of hydrogen sulfide removal under biomethane production in the concept of renewable energy potential growth of Ukraine(EDP Sciences, 2021) Черниш, Єлізавета Юріївна; Chernysh, Yelyzaveta Yuriivna; Bálintová, M.; Чубур, Вікторія Сергіївна; Chubur, Viktoriia SerhiivnaToday, the global trend in the development of renewable energy sources is the implementation of integrated processing of organic waste with the production of biogenic gases such as biomethane. In this case, an essential focus is the study of biogas purification processes to methane. This paper focuses on the process of modeling biochemical purification of biogas from hydrogen sulfide to develop the direction of biomethane production. Simulation of hydrogen sulfide bio-oxidation process with the use of granulated carrier based on phosphogypsum was conducted using experimental data from previous studies to verify the adequacy of the proposed mathematical model. Thus, to implement the process of phosphogypsum utilization in technological systems of biogas purification, it is important to consider the level of bioactivity in the immobilization of bacteria on the loading surface of phosphogypsum and the degree of biotransformation of phosphogypsum components in the oxidation of carbon dioxide and hydrogen sulfide impurities to achieve the highest ecological effect. Also, the use of overlay visualization allowed to form the main clusters of development of research potential in the field of biogas technologies for Ukraine.Item Ecological properties of phosphogypsum and its products: biogeosystem technique for management(Sumy State University, 2022) Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Чубур, Вікторія Сергіївна; Чубур, Виктория Сергеевна; Chubur, Viktoriia Serhiivna; Haneklaus, N.; Roubik, H.In dried form, phosphogypsum is a fine powder, which becomes loose and prone to lump formation, and in the case of long-term storage in a fixed layer, it becomes caked. Hundreds of millions of tons of industrial waste phosphogypsum are available in five regions of Ukraine: Sumy, Kharkiv, Dnepropetrovsk, Rivne, and Cherkassy. The main source of environmental pollution in the areas of mineral fertilizer production (in Ukraine, these are Armyansk, Sumy, and Rivne) is phosphogypsum. The sulfuric acid method of opening the apatite concentrate produces 4,3-5,8 tons of phosphogypsum per 1 ton of H3PO4, depending on the raw materials and the adopted technology. At dry storage of phosphogypsum (without preliminary neutralization), about 10 g of fluorine per 1 ton of phosphogypsum is released into the gas phase, and approximately 10% of fluorine is washed out by atmospheric precipitation. Phosphogypsum should be stored in specially equipped storages isolated from water bodies. Phosphogypsum has to be neutralized with lime milk before it is placed in the storage facility [1]. Conclusions. The issue of phosphogypsum utilization is worth reconsidering by improving the technical solutions and technologies of phosphogypsum disposal to use beneficial constituents of potential value in the life cycle. Regulation of the use of chemical waste needs to be revised, taking the maximum potential of the material, with environmentally friendly cycles closing in phosphogypsum biogeosystem management.Item Methods for Intensifying Biogas Production from Waste: A Scientometric Review of Cavitation and Electrolysis Treatments(MDPI, 2022) Чубур, Вікторія Сергіївна; Чубур, Виктория Сергеевна; Chubur, Viktoriia Serhiivna; Danylov, D.; Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Пляцук, Леонід Дмитрович; Пляцук, Леонид Дмитриевич; Pliatsuk, Leonid Dmytrovych; Shtepa, V.; Haneklaus, N.; Roubik, H.This article presents future trends in research using microbiological methods to intensify bioprocesses for biogas production. The pretreatment by combinations of physical and chemical methods, such as cavitation and electrolysis, is considered. The approach of the article involved reviewing the residual area on the intensification technologies of anaerobic digestion with current methods to improve the quality and quantity of biogas. The most valuable reported positive results of the pretreatment of biological raw materials in the cavitation process were reviewed and are presented here. A model of the effect of electrolysis on the species diversity of bacteria in anaerobic digestion was developed, and changes in the dominance of the ecological and trophic systems were revealed on the basis of previous studies. The stimulating effect on biogas yield, reduction in the stabilization period of the reactor, and inactivation of microorganisms at lower temperatures is associated with different pretreatment methods that intensify anaerobic digestion. More research is recommended to focus on the electrolysis treatment of different types of waste and their ratios with optimization of regime parameters, as well as in combination with other pretreatments to produce biomethane and biohydrogen in larger quantities and in better qualities.Item Anaerobic Digestion Combined with Electrolysis of Poultry Manure and Activated Sludge Inoculum(Institute of Energy, 2022) Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Shtepa, V.N.; Пляцук, Леонід Дмитрович; Пляцук, Леонид Дмитриевич; Pliatsuk, Leonid Dmytrovych; Чубур, Вікторія Сергіївна; Чубур, Виктория Сергеевна; Chubur, Viktoriia Serhiivna; Danylov, D.V.The aim of the work was to study the effect of electrolysis on the process of anaerobic digestion in the example of poultry manure with an inoculum of activated sludge from a municipal wastewater treatment plant. The set aim was achieved by solving the following tasks: microcopiing of anaerobic activated sludge during the digestion of poultry manure under the influence of electrolysis treatment; studying the dynamics of biogas yield and its component composition under electrolysis treatment; studying the change in pH values and redox potential (ORP) in experiments with a combination of a bioreactor with electrolysis treatment and without treatment. Evaluation of the effect of stimulating the metabolic activity of microorganisms during treatment in the bioreactor-electrolyser was the most significant result. In addition, improved biodegradability of complex organic components of poultry manure was substantiated. Thus, methane yield on the 28th day was 640.5 ml from the total volume of 1525 ml of biogas, and under conventional conditions, methane yield was 33.4 ml from 50 ml of total volume. The decrease of H2S content in biogas under the influence of electrolysis was determined. A low ORP value of - 495 mV was achieved in the control experiment (without electrolysis treatment). ORP gradually increased in the bioreactor-electrolyser at all stages of digestion and reached -53 mV on day 28. pH stabilized at a neutral level. The positive effect of combining anaerobic digestion with electrolysis on the intensification of biogas production with a large volume of methane has been experimentally confirmed.Item Effect of Electrolysis on Activated Sludge during the Hydrolysis and Acidogenesis Stages in the Anaerobic Digestion of Poultry Manure(MDPI, 2022) Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Balintova, M.; Shtepa, V.; Чубур, Вікторія Сергіївна; Чубур, Виктория Сергеевна; Chubur, Viktoriia Serhiivna; Junakova, N.This paper focuses on the study of the effect of electrolysis on activated sludge in a microbial electrolysis cell (MEC) under the anaerobic digestion of poultry manure. This study was conducted using a bioreactor design with and without electrodes (conventional condition). Measurements of pH, redox potential (ORP), and total dissolved solids were carried out, as was the microscopy of activated sludge during treatment and gasometry. There was an increase in the yields of CH4 and CO2 compared to conventional conditions. Thus, on the 14th day, there was an increase in the CH4 yield to 35.1% compared with the conventional conditions—31.6%—as well as in the CO2 yield to 53.5% compared with the cell without electrodes—37.7%. Visually, the microscopy of anaerobic activated sludge showed changes in the aggregation process itself, with the formation of cells of clusters of microorganism colonies with branches of a delineated shape. ORP fluctuations were related to the process of the dissociation into ions during the passage of an electric current through the electrodes, and were observed before and after the inclusion of a current into the system. A model of the effect of electrolysis during anaerobic digestion was developed, taking into account the influencing factors on the condition of the activated sludge.Item Rationale for the Combined Use of Biological Processes and AOPs in Wastewater Treatment Tasks(MDPI, 2021) Shtepa, V.; Balintova, M.; Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Чубур, Вікторія Сергіївна; Чубур, Виктория Сергеевна; Chubur, Viktoriia Serhiivna; Demcak, S.; Gautier, M.This paper aims to form a unified concept of the integrated use of different wastewater treatment methods to form a resistant biological treatment stage of technological systems under the influence of such toxic factors as antibiotics and surfactants. The processes of mechanical treatment, ozonation, UV irradiation, and electrolytic anodic oxidation were implemented in an electrotechnological wastewater treatment facility. Wastewater treatment quality was determined by the concentration of nitrogen compounds in aqueous solutions according to the method of Lurie. Biodiagnostics of the investigated activated sludge via surfactant action was carried out at polyethylene oxide concentrations of 10, 30, and 50 mg/dm3. As a result of experiments on wastewater treatment after aquaculture, an improvement in the reduction of pollutants only by the indicator “nitrate concentration” was determined: by 20% after anodic oxidation, and by 15% after photolysis. At almost all surfactant concentrations studied, the activated sludge was not completely recovered, which was expressed in a decrease in its quantity and in the inability to aggregate flakes of activated sludge. The diameter of the growth retardation of the standard disk with antibiotic (amoxiclav) by the accumulative culture of activated sludge was 17.3 ± 2 mm at a concentration of 4 mg/dm3 and 31.3 ± 3 mm at a concentration of 6 mg/dm3. In the process of studying the state of the activated sludge’s biocenosis under the influence of such toxicants, several regularities were revealed. The directions of using combined approaches of water treatment and wastewater treatment were defined. The structural model of treatment facilities using aerobic and anaerobic bioprocesses together with advanced oxidative technologies was substantiated.Item Phosphogypsum Recycling: A Review of Environmental Issues, Current Trends, and Prospects(MDPI, 2021) Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Яхненко, Олена Миколаївна; Яхненко, Елена Николаевна; Yakhnenko, Olena Mykolaivna; Чубур, Вікторія Сергіївна; Чубур, Виктория Сергеевна; Chubur, Viktoriia Serhiivna; Roubík, H.The problem of recycling and storage of phosphogypsum is topical for many countries around the world, as it is associated with environmental problems of pollution of water bodies, land, and atmosphere. Therefore, this paper analyzes the directions of phosphogypsum recycling and possible alternatives to its use. The main disadvantages of the existing methods of phosphogypsum processing were identified and trends in this waste management were also considered. Through the VOSviewer programme, a visualization of cluster interconnections was carried out in research publications of various fields of phosphogypsum utilization. Five clusters were formed: a red cluster—phosphogypsum recycling in the construction industry; green cluster—radiation pollution problem of phosphogypsum and phosphate fertilizers; yellow cluster—monitoring migration of phosphogypsum components in the ecosystem, with the mobile forms of heavy metals and their inflow into aquifers from phosphogypsum dumps; blue cluster—use of phosphogypsum in agriculture as an ameliorant and a component of fertilizer; and a purple cluster—the impact of phosphogypsum on microorganisms, particularly in bioremediation processes. Under the proposed integrated biochemical approach, the use of various bioprocesses of phosphogypsum recovery from waste dumps and implementation of new biotechnological solutions for processing phosphorus raw materials are presented.