Факультет технічних систем і енергоефективних технологій (ТеСЕТ)

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    Comparison of sorption efficiency of natural and MnO2 coated zeolite for copper removal from model solutions
    (IOP Publishing, 2021) Balintova, M.; Kovacova, Z.; Demcak, S.; Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Junakova, N.
    Removal of heavy metals from the environment is important for living beings. The present work investigates the applicability of the natural and MnO2 - coated zeolite as sorbent for the removal of copper from synthetic solutions. Batch experiments were carried out to identify the influence of initial pH and concentration in the process of adsorption. A maximum removal efficiency of Cu(II) was observed in 10 mg/L for natural (95.6%) and modified (96.4%) zeolite, where the values was almost identical, but at concentration of 500 mg/L was the removal efficiency of modified zeolite three times higher. Based on the correlation factors R2, the Langmuir isotherms better describe the decontamination process than Freundlich. The optimum pH value was set at 5.0.
  • Item
    Rationale for the Combined Use of Biological Processes and AOPs in Wastewater Treatment Tasks
    (MDPI, 2021) Shtepa, V.; Balintova, M.; Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Чубур, Вікторія Сергіївна; Чубур, Виктория Сергеевна; Chubur, Viktoriia Serhiivna; Demcak, S.; Gautier, M.
    This paper aims to form a unified concept of the integrated use of different wastewater treatment methods to form a resistant biological treatment stage of technological systems under the influence of such toxic factors as antibiotics and surfactants. The processes of mechanical treatment, ozonation, UV irradiation, and electrolytic anodic oxidation were implemented in an electrotechnological wastewater treatment facility. Wastewater treatment quality was determined by the concentration of nitrogen compounds in aqueous solutions according to the method of Lurie. Biodiagnostics of the investigated activated sludge via surfactant action was carried out at polyethylene oxide concentrations of 10, 30, and 50 mg/dm3. As a result of experiments on wastewater treatment after aquaculture, an improvement in the reduction of pollutants only by the indicator “nitrate concentration” was determined: by 20% after anodic oxidation, and by 15% after photolysis. At almost all surfactant concentrations studied, the activated sludge was not completely recovered, which was expressed in a decrease in its quantity and in the inability to aggregate flakes of activated sludge. The diameter of the growth retardation of the standard disk with antibiotic (amoxiclav) by the accumulative culture of activated sludge was 17.3 ± 2 mm at a concentration of 4 mg/dm3 and 31.3 ± 3 mm at a concentration of 6 mg/dm3. In the process of studying the state of the activated sludge’s biocenosis under the influence of such toxicants, several regularities were revealed. The directions of using combined approaches of water treatment and wastewater treatment were defined. The structural model of treatment facilities using aerobic and anaerobic bioprocesses together with advanced oxidative technologies was substantiated.
  • Item
    Polymer materials: bibliographic data analysis and trend detection
    (National Society of Enviromental Science and Engineeruing, 2021) Черниш, Єлізавета Юріївна; Черныш, Елизавета Юрьевна; Chernysh, Yelyzaveta Yuriivna; Balintova, M.; Рой, Ігор Олександрович; Рой, Игорь Александрович; Roi, Ihor Oleksandrovych; Demcak, S.
    Alternatives to waste management methods include the reorganization, recycling, and creation of environmentally friendly biodegradable polymer materials based on renewable resources, plant, and textile waste. The goal of this study is to analyze bibliographic data and identify trends in research on polymer materials of different genesis, with particular attention to research on the production and use of biopolymers. VOSviewer v.1.6.15 is used to present the analysis results. Environmental impact areas in the life cycle of traditional polymers have been analyzed. The network of main bioplastics clusters is visualized within the framework of modeling the dependencies on the main keywords in the analysis of the dynamics of publication activity, the main trends in the development of new biodegradable materials are revealed. A comparative review of the environmental impact of different types of bioplastics is made by the life cycle assessment method.