Факультет електроніки та інформаційних технологій (ЕлІТ)
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Item Отримання плівок SnO[2] хімічним методом(Сумський державний університет, 2013) Бересток, Таїсія Олександрівна; Бересток, Таисия Александровна; Berestok, Taisiia Oleksandrivna; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid Fedorovych; Мєшков, А.М.Метою дослідження був аналіз відомих методів хімічного осадження плівок SnO2, вибір найбільш оптимального з них та отримання шарів сполуки цим методом.Item Структурні властивості полімерного нанокомпозиту сульфіду цинку з альгінатом(Сумський державний університет, 2015) Опанасюк, Анатолій Сергійович; Опанасюк, Анатолий Сергеевич; Opanasiuk, Anatolii Serhiiovych; Бересток, Таїсія Олександрівна; Бересток, Таисия Александровна; Berestok, Taisiia Oleksandrivna; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid Fedorovych; Мєшков, А.М.Методами растрової електронної мікроскопії, дифрактометрії та рентгено-флуоресцентної спект- рометрії проведено порівняння структурних і субструктурних характеристик плівок чистого сульфіду цинку та біополімеру на основі композиту ZnS з альгінатом. Плівки та наноструктури сульфіду цинку були отримані шляхом хімічного осадження з водного розчину нітрату цинку, тіамочевини та альгі- нату натрію при температурі 90 С та часі синтезу 30-120 хв. Встановлено, що ріст конденсату відбувається шляхом формування наноточок сульфіду цинку з подальшим зарощуванням проміжків між нанозернами частинками альгінату. В результаті розраху- нку полюсної густини та орієнтаційного фактору було підтверджено існування аксіальної текстури [111] як у чистих плівках ZnS так і нанокомпозитах. Показано, що значення сталої гратки конденса- тів чистого ZnS змінювалися в інтервалі а = 0,53266-0,54419 нм, в той час як період гратки шарів ZnS у складі полімерного нанокомпозиту з альгінатом лежав у діапазоні а = 0,53490-0,56261 нм та склад- ним чином залежав від часу синтезу шарів. Встановлено, що середній розмір областей когерентного розсіювання (ОКР) плівок чистого ZnS у кристалографічному напрямі [111] слабо змінювався в усьому діапазоні дослідженого часу осадження (L(111) = 14-29 нм). Для ZnS в складі полімерного нанокомпозиту розмір ОКР лежав в інтервалі L(111) = 21-38 нм, тобто в середньому він був більшим ніж у чистому ZnS.Item Magnetite-polymer Nanoparticles: Structure and Properties(Sumy State University, 2015) Stanislavov, A.S.; Sukhodub, L.B.; Kuznetsov, V.N.; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid FedorovychThe paper describes synthesis of magnetite-alginate composites. The main feature of such biomaterials is the simultaneous formation of magnetite nanoparticles inside the alginate matrix. Obtained samples were characterized by X-ray diffraction and transmission electron microscopy. In several samples the secondary phase of ammonium chloride was observed. The average crystallite sizes of magnetite phase are about 13 nm. The addition of alginate leads to the decrease of microstrains in [h k 0] direction.Item The Study of the Alginate / Hydroxyapatite Composites Structural Properties(Sumy State University, 2014) Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid Fedorovych; Kuznetsov, V.N.; Sukhodub, L.B.This paper describes the synthesis of sodium alginate (Alg) / hydroxyapatite (HA) composites and the influence of the presence of Alg on HA crystallization. Such composites become rather widespread in recent years, and are used in medicine generally for the controlled drug delivery [1‑3]. In one’s case, Alg is used as the functional and cost-effective replacement of the collagen for the creation of implants similar to the natural bone [4]. It was shown that the presence of Alg and the increase of its concentration leads to the decrease of the HA crystallinity thus providing an ability to control its levels in the resulting product. The FTIR studies confirm the incorporation of Alg in the Alg / HA composite structure.Item Alginate-hydroxyapatite Beads for Medical Application(Sumy State University, 2014) Stanislavov, A.; Sukhodub, L.B.; Yanovska, A.A.; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid Fedorovych; Kuznetzov, V.N.The paper describes the synthesis and characterization of alginate-hydroxyapatite (Alg/HA) beads that potentially can be used for drug release due to the adsorptive properties of HA and transmission ability of the soluble compounds through the alginate membrane. Calcium Alg/HA beads were manufactured by dropping of the Alg/HA suspension into CaCl2 solution. Morphology and phase composition of obtained Alg/HA beads were investigated. It was shown that alginate macromolecules influence the hydroxyapatite size and morphology. Obtained HA with crystal size 15-30 nm inside alginate beads correspond a bioapatite size therefore are interesting for the tissue engineering. The main features of alginate-controlled crystallization are discussed in order to understand some aspects in composite material design. Insertion of HA into the alginate microcapsules allows use such materials for production of drug release microspheres.Item The Influence of Ultrasound and Ultraviolet Irradiation on the Nanocomposite Calcium Phosphate-Polymeric Gel(Sumy State University, 2013) Musskaya, O.N.; Kulak, A.I.; Krutsko, V.K.; Ulasevich, S.A.; Lesnikovich, L.A.; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid FedorovychAn influence of high-intensive ultrasound and ultraviolet (UV) irradiation on the nanocomposite calcium phosphate-polymeric gels has been investigated. The action of UV light leads to a significant increase in shear stress and viscosity of hydroxyapatite (HA) / polyvinyl alcohol (PVA) gel while HA / sodium carboxymethyl cellulose (Na-CMC) gel is insensitive to the UV action. Ultrasonic treatment of HA / PVA gel plays an important role only at small shear rates. UV treatment of HA / Na-CMC gel has no effect on its structure and can be used for low temperature UV sterilization. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35469Item Hybrid Hydrogel Materials with Incorporated Nanoparticles(Sumy State University, 2013) Samchenko, Yu.M.; Kryklia, S.O.; Poltoratska, T.P.; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid Fedorovych; Isheikina, Yu.O.; Makarenko, V.I.; Konovalova, V.V.Synthesis and physico-chemical studies of new promising hybrid hydrogels based on polyvinyl alcohol (PVA) acetales and copolymer hydrogels based on vynil monomers have been studied. Acrylamide and Acrylnitrile were used as some of components that carry various fillers . Sponge acetales of polyvinyl alco-hol were used as enforcing net. The synthesized composites demonstrated high strength as compared to standard hydrogels- Yung-module varied in the range of 80 to 300 kPa depending on the extent of PVA ac-etale matrix filling with hydrogel component. The materials showed high sorbability to water and water solutions. Study of swelling kinetics as compared to solvents of various nature (water, ethanol, sunflower oil ) was carried out. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35464Item The Study of the Influence of Static Magnetic Field on Brushite Crystallization in the Presence of Magnesium(Sumy State University, 2013) Kuznetsov, V.N.; Yanovska, A.A.; Stanislavov, A.S.; Danilchenko, S.N.; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid FedorovychThe paper describes the influence of the imposition of static magnetic field on brushite crystallization. Two different configurations of the magnetic field were used. The flasks with the precipitates were placed near the different poles. It was shown that changing the magnetic field configuration and positioning the samples in proximity to north or south poles can greatly affect their crystallinity and texture with most of them having the preferred orientation along the b-axis according to the X-Ray diffraction data. The imposition of the magnetic field also influences the microstrain ratio decreasing it significantly. It was also verified [1] that the Mg substrate availability decreases the crystallinity of DCPD. The micrographs of the nanoparticles with the different magnifications were obtained by the transmission electron microscopy (TEM). The comparative analysis of the electron microscopy data correlates with the XRD data. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35462Item Structural Properties of the Nanocrystallized Magnetite of Different Syntheses(Sumy State University, 2013) Kuznetsov, V.N.; Stanislavov, A.S.; Danilchenko, S.N.; Kalinkevich, O.V.; Kalinkevich, A.N.; Sukhodub, Leonid Fedorovych; Суходуб, Леонід Федорович; Суходуб, Леонид ФедоровичTransmission electron microscopy (TEM) with electronic diffraction and X-ray diffraction (XRD) was used to study structural features of nanosized magnetite Fe3O4, which was synthesized using polymeric matrices (polysaccharide chitosan, at alias). From the received data it was revealed that growth inhibition and size stabilization of Fe3O4 nanoparticles were strongly affected by polysaccharide matrix. It was also observed that directional size decrease of Fe3O4 nanoparticles was accompanied by the increasing defectiveness of crystal lattice and decreasing unit cell size. The effectiveness of complementary use of both TEM with electronic diffraction and XRD techniques for structural and substructural parameters determination while studying magnetite nanosized particles synthesized in polysaccharide matrices is shown in this paper. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35450Item Biphasic Calcium Phosphate Composite for Biomedical Applications(Sumy State University, 2013) Sukhodub, L.B.; Kulak, A.I.; Іншина, Наталія Миколаївна; Иншина, Наталия Николаевна; Inshyna, Nataliia Mykolaivna; Kuznetsov, V.N.; Stanislavov, A.S.; Суходуб, Леонід Федорович; Суходуб, Леонид Федорович; Sukhodub, Leonid FedorovychThe paper describes the preparation of the biphasic (hydroxyapatite (HA) and tricalcium phosphate (TCP)) nanostructured calcium phosphate composite. The product was chemically synthesized from the solution which contained calcium acetate Са(СН3СОО)2 (0,167 mМ), sodium dihydrogen phosphate NaH2PO4 (0,1 mМ), sodium hydrocarbonate NaHCO3 (0,02 mM). The calcium phosphate composite was formed at pH=11 with and without the addition of carbonate ions. The samples were analyzed using X-Ray diffraction after the heat treatment at 900C for 1 h. The derived material contained HA and TCP phases with their contents change depending on the concentration of the carbonate ions in the solution. The mean crystallite size of the HA phase in (121) plane is 12 – 14 nm. Further studies will be directed to the using of the derived composite for the biomedical applications. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35448