Факультет електроніки та інформаційних технологій (ЕлІТ)
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Item Effect of ionly-plasma impact on the element composition and structural phase state of the system of Cu-Ti(Харківський фізико-технічний інститут, 2018) Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Міхалєв, Олександр Дмитрович; Михалев, Александр Дмитриевич; Mikhalev, Alexander Dmitrievich; Jarullah, Aid Kussey; Malikov, L.V.Представлені результати дослідження елементного складу та структурно-фазового стану системи Cu-Ti після впливу високої дози іонної імплантації та електронного відпалювання імпульсним низькоенергетич- ним високострумовим електронним пучком (НВЕП). Встановлено, що застосування імплантації з високою дозою ((5…8)∙1017 іон/см2) і подальшим впливом НВЕП призводить до зменшення концентрації титану, а застосування малої дози до 1∙1017 іон/см2 до його дифузії в глибину від поверхні. Дослідження структурно- фазового стану показало часткове випаровування прошарків карбіду-титану і формування субструктури.Item Specific Features of the Microstructure and Properties of Multielement Nitride Coatings Based on TiZrNbAlYCr(Pleiades Publishing, Ltd., 2018) Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Бондар, Олександр В`ячеславович; Бондарь, Александр Вячеславович; Bondar, Oleksandr Viacheslavovych; Кравченко, Ярослав Олегович; Кравченко, Ярослав Олегович; Kravchenko, Yaroslav Olehovych; Beresnev, V.M.; Zhollybekov, B; Kupchishin, A.I.Multicomponent nanostructured coatings based on (TiZrNbAlYCr)N with a hardness as high as 47 GPa were obtained by cathodic arc deposition. The effect of partial nitrogen pressure PN (with constant bias potential Ub = –200 V applied to the substrate) on the phase-composition variation, the size of crystallites, and their relation to the microstructure and hardness was investigated. An increase in the nitrogen pressure resulted in the formation of two phases with characteristic BCC (the lattice period is 0.342 nm) and FCC lattices with averaged nanocrystallite sizes of 15 and 2 nm. At a high pressure of 0.5 Pa, crystallites in the FCC phase with a lattice period of 0.437 nm grew in size to ~7 nm. The hardness of deposited coatings with larger (3.5 nm) FCC-phase crystallites and smaller (7 nm) BCC-phase crystallites was enhanced considerablyItem Structural Features and Tribological Properties of Multilayer Coatings Based on Refractory Metals(Pleiades Publishing, Ltd, 2018) Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Кравченко, Ярослав Олегович; Кравченко, Ярослав Олегович; Kravchenko, Yaroslav Olehovych; Бондар, Олександр В`ячеславович; Бондарь, Александр Вячеславович; Bondar, Oleksandr Viacheslavovych; Zhollybekov, B.; Kupchishin, A.I.A comparative analysis of the structural features and tribological properties of multilayer coatings based on refractory metal compounds has been conducted in this review. Features of formation of the elec- tronic structure of the synthesized coatings have been discussed, and the effect of methods and conditions of deposition on changes in the physicomechanical characteristics of nanocrystalline structures based on tran- sition metal nitrides has been shown. Dependences of antifriction properties, corrosion resistance, and ther- mal stability on the modulation period (Λ) and the number of bilayers in the studied multilayer coatings have been determined. A decrease in the modulation period of individual layers in a coating positively affects the oxidation resistance of the coating, while an increase in the number of interfaces between the layers slows down the diffusion of oxygen atoms deep into the coating and, thereby, increases the protective properties of the multilayer system as a whole. The effect of the droplet component in cathodic-arc coatings on corrosion development mechanisms in corrosive media has been shown. A class of multifunctional multilayer coatings with an adaptive friction mechanism, which is characterized by a change in the properties and structure during tribological tests, has been discussed separately.Item Structure and Mechanical Properties of TiAlSiY Vacuum-Arc Coatings Deposited in Nitrogen Atmosphere(Pleiades Publishing, Ltd, 2018) Beresnev, V.M.; Sobol, O.V.; Lytovchenko, S.V.; Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Klimenko, S.A.; Stolbovoy, V.A.; Srebniuk, P.A.; Manokhin, A.S.; Kovaleva, M.G.; Novikov, V.Yu.; Meilekhov, A.A.; Nyemchenko, U.S.; Barmin, A.E.; Turbin, P.V.The effect of a negative bias potential applied to the substrate on elemental composition, structure, and mechanical properties of vacuum-arc TiAlSiY nitride coatings is investigated by different methods. It is ascertained that applying a high (up to –500 V) bias voltage leads to a selective sputtering of target as well as significant microdeformation of the coating, small-sized growth of crystallites, and their preferred orientation along the [110] direction. In this case, the coating deposited has a low hardness H = 6.95 GPa and propensity to intense wear under scratch and tribological tests. Crystallites with stoichiometric composition ~140 nm in size and [111] preferred orientation perpendicular to the surface of growth are formed at the bias potential about –200 V, and superhard (H = 49.5 GPa) and wear-resistant coatings are grown under such conditions. The mechanisms of formation of the structure of multielement coatings are discussed. It is shown that for- mation of an amorphous phase and nanocrystal [110] texture takes place at a high bias potential owing to the process of radiation-stimulated selective spraying of the target. Formation of microstrained crystallites 10 nm in size caused by the weakening of interatomic bonds is observed in the coating under such deposition condi- tions, and it leads to the decrease in coating hardness and fast destruction during tribological testing. Sub- stantial bias voltage dependence of deposited coating properties is established in our investigations.Item Features of Investigations of Multilayer Nitride Coatings Based on Cr and Zr(G.V. Kurdyumov Institute for Metal Physics, National Academy of Sciences of Ukraine, 2018) Максакова, Ольга Василівна; Максакова, Ольга Васильевна; Maksakova, Olga Vasylivna; Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Beresnev, V.M.У короткому огляді літературних даних узагальнено результати дослі- джень структури та властивостей наномасштабних багатошарових пок- риттів тугоплавких металів на основі Zr та Cr одержаних методами ва- куумно-дугового осадження катоду. Проведено порівняльну аналізу мі- кроструктури та властивостей композиційних покриттів ZrN/CrN в за- лежності від умов осадження (постійного неґативного потенціялу під- ложжя, імпульсного високовольтного потенціялу зміщення, парціяль- ного тиску і швидкости потоку робочого газу) та періоду модуляції ба- гатошарової структури. Виявлено загальні закономірності, що поляга- ють у наявності стовпчастої структури та текстури росту. Показано, що для досліджуваних покриттів має місце переважна орієнтація (111). Визначено умови одержання покращених фізико-механічних та трибо- логічних властивостей покриттів.Item Structural and mechanical characterization of (TiZrNbHfTa)N/WN multilayered nitride coatings(Elsevier, 2018) Багдасарян, Артем Анатолійович; Багдасарян, Артем Анатольевич; Bahdasarian, Artem Anatoliiovych; Pshyk, A.V.; Coy, L.E.; Kempinski, M.; Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Beresnev, V.M.; Jurga, S.The (TiZrNbHfTa)N/WN multicomponent coatings were deposited by vacuum arc evaporation under dif- ferent substrate bias (-90 and -280 V).X-ray photoelectron spectroscopy was used for analyzing of com- plex composition of investigated coatings by reflecting of atomic scale chemical interactions. The structural investigations showed the formation of a simple disordered solid solution in (TiZrNbHfTa)N layer, b-W2N phase in WN layer with fcc crystal structure and highly disordered bcc (110) and (220) -oriented high-entropy alloy phases, regardless of the applied bias potential. It was shown that with increasing of substrate bias from -90 to -280 V, there is a slight decrease of hardness from 34 to 31 GPa and increase of Young’s modulus from 325 to 337 GPa, which can be explained by annihilation of point defects and precipitation of relatively softer metallic phase.Item Experimental and theoretical studies of the physicochemical and mechanical properties of multi-layered TiN/SiC films: Temperature effects on the nanocomposite structure(Elsevier, 2018) Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Ivashchenko, V.I.; Skrynskyy, P.L.; Konarski, P.; Бондар, Олександр В`ячеславович; Бондарь, Александр Вячеславович; Bondar, Oleksandr Viacheslavovych; Zaleski, Karol; Jurga, Stefan; Coy, EmersonNanoscale multilayered TiN/SiC films are of great importance in many electronic and industrial fields. The careful control over the structure of the laminates, nanocrystalline or amorphous, is crucial for their further applicability and study. However, several limitations in their fabrication have revealed important gaps in the understanding of this system. Here, we study influence of temperature on the physico-chemical and functional properties of TiN/SiC multilayers. We will show the clear increment on hardness of the samples, while the nanocomposite structure of the layers is maintained with no increment in crystal size. We will investigate the interstitial effects and rearrangements, between the TiN/SiC phases and their role in the enhanced mechanical response. Our experiments will clearly show a change in the modulation period of the samples, pointing to interfacial reactions, diffusion of ions or crystallization of new phases. Full Investigations of the film properties were carried out using several methods of analysis: XRD, XPS, FTIR, HR-TEM and SIMS Additionally, results were combined with First Principles MD computations of TiN/SiC heterostructures.Item A new type of (TiZrNbTaHf)N/MoN nanocomposite coating: Microstructure and properties depending on energy of incident ions(Elsevier, 2018) Багдасарян, Артем Анатолійович; Багдасарян, Артем Анатольевич; Bahdasarian, Artem Anatoliiovych; Pshyk, A.V.; Coy, L.E.; Konarski, P; Misnik, M; Ivashchenko, V.I.; Kempinski, M; Mediukh, N.R.; Beresnev, V.M.; Jurga, S; Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr DmytrovychA novel (TiZrNbTaHf)N/MoN nanocomposite coatings, which consist of the nitride of the high-entropy alloy and the binary nitride, were synthesized by vacuum-arc deposition at various substrate biases. The elemental composition, chemical bonding state, phase structure, microstructure and mechanical properties of the coatings were studied by high-resolution experimental methods: SIMS, GDMS, XPS, XRD, HR-TEM and nano-indentation.It was found that the chemical state of the (TiZrNbTaHf)N/MoN coatings has a complex nature, which consist of a mixture of nitrides of constituting elements. It was also shown that the coatings are based on B1 NaCl-structured γ-Mo2N-phase with a mixture of crystallographic orientations (111), (200), (220) and (311) together with the B1NaCl-structured (TiZrNbTaHf)N solid-solution phase. First-principles calculations demonstrated that the metal sub-lattice of the (TiZrNbTaHf)N solid solution can be based on Ti1-xHfyTa1-x-y, Zr1-xHfyTa1-x-y, Zr0.25Ti0.25Ta0.5 ternary alloys, which have the lowest mixing energy. The HR-TEM results showed that the nanocomposite nitride coatings have nano-scale multilayer structure with modulation periods ranged from 20nm to 25nm. The maximum hardness of approximately 29GPa demonstrated the coating deposited at a higher energy condition (−200V) with the thinnest modulation period of bilayer of 20nm (15nm of (TiZrNbTaHf)N and 5nm of Mo2N).Item Microstructure and tribological properties of nitride coatings based on Zr, Ti, Cr, Nb, and Si elements(Beggel House, 2017) Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Багдасарян, Артем Анатолійович; Багдасарян, Артем Анатольевич; Bahdasarian, Artem Anatoliiovych; Beresnev, V.M.; Kupchishin, A.I.; Plotnikov, S.V.; Кравченко, Ярослав Олегович; Кравченко, Ярослав Олегович; Kravchenko, Yaroslav OlehovychThe structure and tribological properties of the nitride coatings (Zr–Ti–Nb)N, (Zr–Ti–Cr–Nb)N, and (Zr–Ti-Cr–Nb–Si)N, f abricated by vacuum arc deposition have been investigated. Their ele- mental composition and crystal structure are characterized by EDS and SEM analyses, XPS, and X-ray diffraction. The multicomponent (Zr–Ti–Cr–Nb–Si)N and (Zr–Ti–Nb)N coatings are f ound to be a simple f ace-centered cubic (f cc) solid solution. For the coatings without Si, the struc- ture is mainly composed of the TiN f cc phase and Cr2N trigonal modification. The (Zr–Ti–Nb)N and (Zr–Ti–Cr–Nb)N coatings provided the best adhesive strength in different conditions. The (Zr–Ti–Cr–Nb–Si)N coatings exhibited the worst adhesive strength, which may be attributed to the relative low hardness.Item The effects of Cr and Si additions and deposition conditions on the structure and properties of the (Zr-Ti-Nb)N coatings(Elsevier, 2017) Погребняк, Олександр Дмитрович; Погребняк, Александр Дмитриевич; Pohrebniak, Oleksandr Dmytrovych; Багдасарян, Артем Анатолійович; Багдасарян, Артем Анатольевич; Bahdasarian, Artem Anatoliiovych; Кравченко, Ярослав Олегович; Кравченко, Ярослав Олегович; Kravchenko, Yaroslav Olehovych; Beresnev, V.M.; Nyemchenko, U.S.; Ivashchenko, V.I.; Shaimardanov, ZH.K.; Plotnikov, S.V.; Maksakova, O.In this study, (Zr-Ti-Nb)N, (Zr-Ti-Cr-Nb)N and (Zr-Ti-Cr-Nb-Si)N nitride coatings were obtained using a well-developed vacuum arc deposition. The systematical investigations demonstrate that the chemical composition, microstructure, and properties of the coatings intimately rely on the deposition parameters (pressure of working gas and substrate bias). Effects of Cr and Si additions on microstructure and mechanical properties of the (Zr-Ti-Nb)N coatings have been investigated using scanning electron microscopy (SEM) equipped with energy dispersive spectrum (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), transmission electron microscope (TEM), hardness measurements and adhesion testing. First-principles band-structure calculations and Gibbs-Rosenbaum triangle representation have been used to investigate the elemental and phase compositions in nitride coatings. The multi-component (Zr-Ti-Cr-Nb-Si)N and (Zr-Ti-Nb)N coatings are found to be a simple face-centered cubic (FCC) solid solution. For the coatings without Si, the structure is mainly composed of TiN fcc phase and Cr2N trigonal modification. The hardness values were in the ranges (24–42 GPa). The (Zr-Ti-Nb)N, (Zr-Ti-Cr-Nb)N coatings provided the best adhesive strength in different conditions. The (Zr-Ti-Cr-Nb-Si)N coatings exhibited the worst adhesive strength, which may be attributed to the relative low hardness.