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Title Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase
Authors Sehin, M.Ya.
Tkachuk, A.I.
Keywords Degree of intercalation
Anatase
Laser irradiation
Specific capacitance
Type Conference Papers
Date of Issue 2012
URI http://essuir.sumdu.edu.ua/handle/123456789/35243
Publisher Sumy State University
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Citation Sehin, M.Ya. Thermodynamic Parameters of the Intercalation Reaction in Thermal and Laser Modified Nanodispersed Anatase / M. Y. Sehin, A. I. Tkachuk // Nanomaterials: Applications & Properties (NAP-2012) : 2-nd International conference, Alushta, the Crimea, September 17-22, 2012 / Edited by: A. Pogrebnjak. - Sumy : Sumy State University, 2012. - V. 1, No4. - 04NEA02
Abstract It is modified matrix of anatase in turn of the thermal and laser treatments. The dependence of Gibbs energy change of the intercalation reaction of lithium with the guest load degree change was analyzed. Laser irradiation turned out to increase twice the value of maximum lithium “guest” loading, constricting heterophase area and changing contrarily concentration genesis of temperature dependence of entropy of lithium dilution. The optimal conditions of laser irradiation nanodispersive anatase (pulse energy E 0,02 J, pulse duration τ 15 ns repetition frequency f 28 Hz, duration of exposure to 5 min.), at which specific energy characteristics of LPS, formed on its basis, increased by 55% is set. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/35243
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