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Title Direct Synthesis of O-doped Carbon Nitride and Oxide of Graphite-like Carbon Nitride from Melamine
Authors Kharlamov, A.I.
Bondarenko, M.E.
Kharlamova, G.A.
Fomemko, V.V.
ORCID
Keywords O-doped carbon nitride
Oxide of graphite-like carbon nitride
Pyrolysis
Synthesis
Melamine
Type Conference Papers
Date of Issue 2015
URI http://essuir.sumdu.edu.ua/handle/123456789/42601
Publisher Sumy State University
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Citation Direct Synthesis of O-doped Carbon Nitride and Oxide of Graphite-like Carbon Nitride from Melamine [Текст] / A.I. Kharlamov, M.E. Bondarenko, G.A. Kharlamova, V.V. Fomenko // Nanomaterials: Applications & Properties (NAP-2015) : Proceedings of the International Conference. — Sumy : Sumy State University, 2015. — V.4, No1. — 01NNPT02.
Abstract It was first performed a special method of pyrolysis of melamine in order to study the possibility of coproduction of carbon nitride and its oxidized derivatives. New compound as a graphite-like carbon nitride oxide (g-C3N4)O, which is isostructural analogue of graphite oxide, and doped with oxygen ( ~ 8.1 % ), carbon nitride (O-g-C3N4) were obtained. In contrast to known methods for the preparation of samples doped with oxygen carbon nitride a new route does not provide a preliminary synthesis of g-C3N4.The synthesized carbon nitride oxide is easily stratified and dissolved in water to form a flocculent solution which may contain not only ultra-thin nanosheets from several heptazine oxidized layers, but also the individual twodimensional monolayers. These monolayers can be a precursor for making reduced heptazine monolayer (or azagraphene). The synthesized substunces were investigated by methods chemical and X-ray analyses, IR spectroscopy, temperature-programmed desorption mass spectrometry (TPDMS) obtained products.
Appears in Collections: Наукові видання (ЕлІТ)

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